Osmium tetroxide-catalysed cis-hydroxylation of 5-vinyl-4,5- dihydroisoxazoles proceeds stereoselectively affording the anti-products in fair to excellent diastereoisomeric excess; an entry to optically active compounds is also described.
STEREOSELECTIVE OSMYLATION OF 5-VINYL-4,5-DIHYDROISOXAZOLES / R. ANNUNZIATA, M. CINQUINI, F. COZZI, L. RAIMONDI. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - 7(1985), pp. 403-405. [10.1039/c39850000403]
STEREOSELECTIVE OSMYLATION OF 5-VINYL-4,5-DIHYDROISOXAZOLES
R. AnnunziataPrimo
;M. CinquiniSecondo
;F. CozziPenultimo
;L. RaimondiUltimo
1985
Abstract
Osmium tetroxide-catalysed cis-hydroxylation of 5-vinyl-4,5- dihydroisoxazoles proceeds stereoselectively affording the anti-products in fair to excellent diastereoisomeric excess; an entry to optically active compounds is also described.
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