During experiments on the transesterification of vinyl benzoate with ethanol mediated by IPr and IMes, unexpected species were observed and characterized that call into question the accepted mechanism of the NHC-mediated transesterification of vinyl esters.
Unusual Mechanistic Course of Some NHC-Mediated Transesterifications / L. Pignataro, T. Papalia, A. M. Z. Slawin, S. M. Goldup. - In: ORGANIC LETTERS. - ISSN 1523-7060. - 11:7(2009), pp. 1643-1646.
Unusual Mechanistic Course of Some NHC-Mediated Transesterifications
L. Pignataro;
2009
Abstract
During experiments on the transesterification of vinyl benzoate with ethanol mediated by IPr and IMes, unexpected species were observed and characterized that call into question the accepted mechanism of the NHC-mediated transesterification of vinyl esters.
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