The irreversible transesterification of racemic 2-methyl-1,3-propanediol derivatives, the monoethers 3a, 3b, 5a, and the monobenzoate 5b, with vinyl acetate catalyzed by Pseudomonas fluorescens lipase in chloroform affords enantiomerically pure chiral synthons.
ENANTIOSELECTIVE TRANSESTERIFICATION OF 2-METHYL-1,3-PROPANEDIOL DERIVATIVES CATALYZED BY PSEUDOMONAS-FLUORESCENS LIPASE IN AN ORGANIC-SOLVENT / P. GRISENTI, P. FERRABOSCHI, A. MANZOCCHI, E. SANTANIELLO. - In: TETRAHEDRON. - ISSN 0040-4020. - 48:18(1992), pp. 3827-3834. [10.1016/S0040-4020(01)92273-2]
ENANTIOSELECTIVE TRANSESTERIFICATION OF 2-METHYL-1,3-PROPANEDIOL DERIVATIVES CATALYZED BY PSEUDOMONAS-FLUORESCENS LIPASE IN AN ORGANIC-SOLVENT
P. FerraboschiSecondo
;A. ManzocchiPenultimo
;E. SantanielloUltimo
1992
Abstract
The irreversible transesterification of racemic 2-methyl-1,3-propanediol derivatives, the monoethers 3a, 3b, 5a, and the monobenzoate 5b, with vinyl acetate catalyzed by Pseudomonas fluorescens lipase in chloroform affords enantiomerically pure chiral synthons.
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