The novel anion [Rh23N4(CO)20(μ-CO) 18]3-, obtained by controlled pyrolysis of [Rh 6N(CO)15]-, contains a large metallic polyhedron of idealized C2 symmetry, which has 21 surface metals and encloses a couple of bonded rhodium atoms and four interstitial nitrogen atoms, each connected to five rhodium atoms.

A large rhodium carbonyl cluster compound containing four encapsulated nitrogen atoms: Synthesis and X-ray structure of the anion [Rh 23N4(CO)20(μ-CO)18]3 / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :19(1992), pp. 1405-1406. [10.1039/C39920001405]

A large rhodium carbonyl cluster compound containing four encapsulated nitrogen atoms: Synthesis and X-ray structure of the anion [Rh 23N4(CO)20(μ-CO)18]3

G. Ciani;A. Sironi
1992

Abstract

The novel anion [Rh23N4(CO)20(μ-CO) 18]3-, obtained by controlled pyrolysis of [Rh 6N(CO)15]-, contains a large metallic polyhedron of idealized C2 symmetry, which has 21 surface metals and encloses a couple of bonded rhodium atoms and four interstitial nitrogen atoms, each connected to five rhodium atoms.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/179720
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