Phthalimidomethyl and phenoxymethyl as well as corresponding acetyl cobalt tetracarbonyls (1-4) were prepared and characterized. The single-crystal X-ray diffraction molecular structure of 1 (the first X-ray structure of an alkylcobalt tetracarbonyl with a pure organic alkyl group) was determined. The equilibrium constants of the equilibria 1 half arrow pointing right over half arrow pointing left 2 and 3 half arrow pointing right over half arrow pointing left 4 were determined at 20-60 and 20-40 degrees C, respectively.
|Titolo:||(Phthalimidomethyl)- and (phenoxymethyl)cobalt carbonyls. Equilibria of CO insertion|
|Settore Scientifico Disciplinare:||Settore CHIM/03 - Chimica Generale e Inorganica|
|Data di pubblicazione:||1997|
|Digital Object Identifier (DOI):||10.1021/OM9700066|
|Appare nelle tipologie:||01 - Articolo su periodico|