The compound [La(pmtz)(TzC)(H 2O) 3](H 2O) (pmtz = 5-(pyrimidyl)-tetrazolato, TzC = 5-carboxylato-tetrazolato) has been prepared under hydrothermal conditions and exhibits a 3D diamondoid network. This three-dimensional metal-organic framework has channels with hosted water molecules inside and shows an intense blue-greenish long lifetime photoluminescence emission at room temperature in the solid state with two lifetime decay values of 0.26 and 27 ms. © The Royal Society of Chemistry 2010.
A chiral diamondoid 3D lanthanum metal-organic framework displaying blue-greenish long lifetime photoluminescence emission / A. Rodríguez-Diéguez, A. Salinas-Castillo, A. Sironi, J. M. Seco, E. Colacio. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 12:6(2010), pp. 1876-1879.
A chiral diamondoid 3D lanthanum metal-organic framework displaying blue-greenish long lifetime photoluminescence emission
A. Sironi;
2010
Abstract
The compound [La(pmtz)(TzC)(H 2O) 3](H 2O) (pmtz = 5-(pyrimidyl)-tetrazolato, TzC = 5-carboxylato-tetrazolato) has been prepared under hydrothermal conditions and exhibits a 3D diamondoid network. This three-dimensional metal-organic framework has channels with hosted water molecules inside and shows an intense blue-greenish long lifetime photoluminescence emission at room temperature in the solid state with two lifetime decay values of 0.26 and 27 ms. © The Royal Society of Chemistry 2010.Pubblicazioni consigliate
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