The polymeric compound [Ag-2(bpethy)(5)](BF4)(2), obtained from AgBF4 and 1,2-bis(4-pyridyl)ethyne (bpethy) in molar ratio 1:3, contains infinite molecular ladder motifs with monodentate ligands as sidearms on both sides, that are threaded through the squares of adjacent polymeric units in a mutual relationship, to give infinite 'polythreaded' bidimensional layers.
A new type of supramolecular entanglement in the silver(I) coordination polymer [Ag-2(bpethy)(5)](BF4)(2) [bpethy = 1,2-bis(4-pyridyl)ethyne] / L. Carlucci, G. Ciani, D.M. Proserpio. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 5(1999), pp. 449-450. [10.1039/a809361j]
A new type of supramolecular entanglement in the silver(I) coordination polymer [Ag-2(bpethy)(5)](BF4)(2) [bpethy = 1,2-bis(4-pyridyl)ethyne]
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioUltimo
1999
Abstract
The polymeric compound [Ag-2(bpethy)(5)](BF4)(2), obtained from AgBF4 and 1,2-bis(4-pyridyl)ethyne (bpethy) in molar ratio 1:3, contains infinite molecular ladder motifs with monodentate ligands as sidearms on both sides, that are threaded through the squares of adjacent polymeric units in a mutual relationship, to give infinite 'polythreaded' bidimensional layers.File in questo prodotto:
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