Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200 degrees C have resulted in [La(ethylenediamine)(4)Cl]In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group I4 (No. 79) a=13.471(3), c=7.295(3) Angstrom, Z=2.1 is a Zintl compound containing one-dimensional polymeric chains of [GRAPHICS] built of InTe4 tetrahedra sharing opposite edges, and [La(en)(4)Cl](2+) (ethylenediamine=en) cations with regular monocapped square-antiprism nona-coordination.

Solvothermal synthesis and crystal structure of [La(ethylenediamine)(4)Cl]In2Te4: A 1-D indium telluride / Z. Chen, J. Li, F. Chen, D.M. Proserpio. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 273:1-2(1998), pp. 255-258.

Solvothermal synthesis and crystal structure of [La(ethylenediamine)(4)Cl]In2Te4: A 1-D indium telluride

D.M. Proserpio
Ultimo
1998

Abstract

Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200 degrees C have resulted in [La(ethylenediamine)(4)Cl]In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group I4 (No. 79) a=13.471(3), c=7.295(3) Angstrom, Z=2.1 is a Zintl compound containing one-dimensional polymeric chains of [GRAPHICS] built of InTe4 tetrahedra sharing opposite edges, and [La(en)(4)Cl](2+) (ethylenediamine=en) cations with regular monocapped square-antiprism nona-coordination.
Crystal structures; Solvothermal reactions; Tellurides
Settore CHIM/03 - Chimica Generale e Inorganica
1998
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/178783
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