Very large free voids (more than 50% of the cell volume) and interesting stuctural motifs are found in the 2D and 3D frameworks assembled using AgNO3 and 5,10,15,20-tetra(4-pyridyl) porphyrin (H2tpyp) building blocks. The robust 3D network of [Ag8(ZnIItpyp)7 (H2O)2](NO3)8 is particularly fascinating in that it exhibits a unique self-penetrating topology (see figure) and can be reversibly desolvated.

Open network architectures from the self-assembly of AgNO3 and 5,10,15,20-tetra(4pyridyl)porphyrin (H(2)tpyp) building blocks: The exceptional self-penetrating topology of the 3D network of [Ag-8(Zn(II)tpyp)(7)(H2O)(2)](NO3)(8) / L. Carlucci, G. Ciani, D.M. Proserpio, F. Porta. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 42:3(2003), pp. 317-322.

Open network architectures from the self-assembly of AgNO3 and 5,10,15,20-tetra(4pyridyl)porphyrin (H(2)tpyp) building blocks: The exceptional self-penetrating topology of the 3D network of [Ag-8(Zn(II)tpyp)(7)(H2O)(2)](NO3)(8)

L. Carlucci;G. Ciani;D.M. Proserpio;F. Porta
2003

Abstract

Very large free voids (more than 50% of the cell volume) and interesting stuctural motifs are found in the 2D and 3D frameworks assembled using AgNO3 and 5,10,15,20-tetra(4-pyridyl) porphyrin (H2tpyp) building blocks. The robust 3D network of [Ag8(ZnIItpyp)7 (H2O)2](NO3)8 is particularly fascinating in that it exhibits a unique self-penetrating topology (see figure) and can be reversibly desolvated.
Coordination polymer; Nanostructures; Networks; Porphyrinoids; Silver
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/178758
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