Three structural motifs have been obtained by using the novel building block trans-[RuCl2(pyz)4] with different silver salts: A two-dimensional network with an unprecedented double-honeycomb topology, a three-dimensional array with the rutile (6,3) structure, and an interesting tetragonal network with both Ru and Ag in octahedral environments, which can be related to the rock-salt topology (see picture).

Crystal engineering of mixed-metal Ru-Ag coordination networks by using the trans-[RuCl2(PYZ)(4)] (pyz = pyrazine) building block / L. Carlucci, G. Ciani, F. Porta, D.M. Proserpio, L. Santagostini. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 41:11(2002), pp. 1907-1911.

Crystal engineering of mixed-metal Ru-Ag coordination networks by using the trans-[RuCl2(PYZ)(4)] (pyz = pyrazine) building block

L. Carlucci;G. Ciani;F. Porta;D.M. Proserpio;L. Santagostini
2002

Abstract

Three structural motifs have been obtained by using the novel building block trans-[RuCl2(pyz)4] with different silver salts: A two-dimensional network with an unprecedented double-honeycomb topology, a three-dimensional array with the rutile (6,3) structure, and an interesting tetragonal network with both Ru and Ag in octahedral environments, which can be related to the rock-salt topology (see picture).
Coordination polymers; N ligands; Ruthenium; Silver
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/178588
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