The novel bidimensional coordination polymers [Zn(azpy)(2)(H2O)(2)]SiF6. H2O and [Ni(azpy)(2)(NO3)(2)](2)[Ni-2(azpy)(3)(NO3)(4)]. 4CH(2)Cl(2), assembled with trans-4,4'-azobis(pyridine) (azpy), show inclined interpenetration of their layers, i.e. (4,4) planes in the former species, and (4,4) and (6,3) planes, in the second one, which represents the first example of intertwining of different two-dimensional coordination motifs.
Three-dimensional architectures of intertwined planar coordination polymers: the first case of interpenetration involving two different bidimensional polymeric motifs / L. Carlucci, G. Ciani, D.M. Proserpio. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - 22:12(1998), pp. 1319-1321.
Three-dimensional architectures of intertwined planar coordination polymers: the first case of interpenetration involving two different bidimensional polymeric motifs
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioUltimo
1998
Abstract
The novel bidimensional coordination polymers [Zn(azpy)(2)(H2O)(2)]SiF6. H2O and [Ni(azpy)(2)(NO3)(2)](2)[Ni-2(azpy)(3)(NO3)(4)]. 4CH(2)Cl(2), assembled with trans-4,4'-azobis(pyridine) (azpy), show inclined interpenetration of their layers, i.e. (4,4) planes in the former species, and (4,4) and (6,3) planes, in the second one, which represents the first example of intertwining of different two-dimensional coordination motifs.
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