Both co-ordinative and hydrogen bonds contribute to networking in a series of polymeric compounds based on [M(bipy)] (bipy = 4,4'-bipyridyl) linear chains, which, through metal-co-ordinated water molecules and solvated bipy bases, have been shown to be cross-linked by single or double hydrogen-bond bridges of the type M-H2O...bipy... H2O-M, producing extended frames.
Extended networks via hydrogen bond cross-linkages of [M(bipy)] (M=Zn2+ or Fe2+; bipy=4,4'-bipyridyl) linear co-ordination polymers / L. Carlucci, G. Ciani, D.M. Proserpio, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - 1997:11(1997), pp. 1801-1803. [10.1039/a702146a]
Extended networks via hydrogen bond cross-linkages of [M(bipy)] (M=Zn2+ or Fe2+; bipy=4,4'-bipyridyl) linear co-ordination polymers
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioPenultimo
;A. SironiUltimo
1997
Abstract
Both co-ordinative and hydrogen bonds contribute to networking in a series of polymeric compounds based on [M(bipy)] (bipy = 4,4'-bipyridyl) linear chains, which, through metal-co-ordinated water molecules and solvated bipy bases, have been shown to be cross-linked by single or double hydrogen-bond bridges of the type M-H2O...bipy... H2O-M, producing extended frames.
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