Both co-ordinative and hydrogen bonds contribute to networking in a series of polymeric compounds based on [M(bipy)] (bipy = 4,4'-bipyridyl) linear chains, which, through metal-co-ordinated water molecules and solvated bipy bases, have been shown to be cross-linked by single or double hydrogen-bond bridges of the type M-H2O...bipy... H2O-M, producing extended frames.

Extended networks via hydrogen bond cross-linkages of [M(bipy)] (M=Zn2+ or Fe2+; bipy=4,4'-bipyridyl) linear co-ordination polymers / L. Carlucci, G. Ciani, D.M. Proserpio, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - 1997:11(1997), pp. 1801-1803. [10.1039/a702146a]

Extended networks via hydrogen bond cross-linkages of [M(bipy)] (M=Zn2+ or Fe2+; bipy=4,4'-bipyridyl) linear co-ordination polymers

L. Carlucci
Primo
;
G. Ciani
Secondo
;
D.M. Proserpio
Penultimo
;
A. Sironi
Ultimo
1997

Abstract

Both co-ordinative and hydrogen bonds contribute to networking in a series of polymeric compounds based on [M(bipy)] (bipy = 4,4'-bipyridyl) linear chains, which, through metal-co-ordinated water molecules and solvated bipy bases, have been shown to be cross-linked by single or double hydrogen-bond bridges of the type M-H2O...bipy... H2O-M, producing extended frames.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/178506
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