Cu(II) triflate reacts with 4,4 -bipyridyl in different solvents to yield the new 3D network [Cu(4,4-bipy)(2)(CF3SO3)(2)], based on pseudo-square planar nodes and consisting of crossing layers of large rhombic meshes (22 x 22 Angstrom) fused together into an overall (two-fold interpenetrated) array, with a topology unprecedented within coordination frames and an interesting nanoporous behaviour.
A three-dimensional nanoporous flexible network of 'square-planar' copper(II) centres with an unusual topology / L. Carlucci, N. Cozzi, G. Ciani, M. Moret, D.M. Proserpio, S. Rizzato. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - :13(2002), pp. 1354-1355.
A three-dimensional nanoporous flexible network of 'square-planar' copper(II) centres with an unusual topology
L. CarlucciPrimo
;G. Ciani;D.M. ProserpioPenultimo
;S. RizzatoUltimo
2002
Abstract
Cu(II) triflate reacts with 4,4 -bipyridyl in different solvents to yield the new 3D network [Cu(4,4-bipy)(2)(CF3SO3)(2)], based on pseudo-square planar nodes and consisting of crossing layers of large rhombic meshes (22 x 22 Angstrom) fused together into an overall (two-fold interpenetrated) array, with a topology unprecedented within coordination frames and an interesting nanoporous behaviour.
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