Three novel coordination polymers, [AS(N-N)(2)]X (N-N = 4,4'-bipyridyl, X = CF(3)SO(3)(-)1; N-N = 4-cyanopyridine, X = BF4-, in two polymorphs, 2 and 3)], are prepared and investigated by single crystal X-ray analysis; 1 and 2 contain three-dimensional cationic frameworks, both consisting of four equivalent interpenetrating diamondoid lattices, while 3 is formed by two-dimensional layers of distorted squares.
INTERPENETRATING DIAMONDOID FRAMEWORKS OF SILVER(I) CATIONS LINKED BY N,N'-BIDENTATE MOLECULAR RODS / L. CARLUCCI, G. CIANI, D.M. PROSERPIO, A. SIRONI. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :24(1994), pp. 2755-2756.
INTERPENETRATING DIAMONDOID FRAMEWORKS OF SILVER(I) CATIONS LINKED BY N,N'-BIDENTATE MOLECULAR RODS
L. CARLUCCIPrimo
;G. CIANISecondo
;D.M. PROSERPIOPenultimo
;A. SIRONIUltimo
1994
Abstract
Three novel coordination polymers, [AS(N-N)(2)]X (N-N = 4,4'-bipyridyl, X = CF(3)SO(3)(-)1; N-N = 4-cyanopyridine, X = BF4-, in two polymorphs, 2 and 3)], are prepared and investigated by single crystal X-ray analysis; 1 and 2 contain three-dimensional cationic frameworks, both consisting of four equivalent interpenetrating diamondoid lattices, while 3 is formed by two-dimensional layers of distorted squares.
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