The reaction of cobalt(II) sulfate with 1,2-bis(4-pyridyl)ethane gives a crystalline polymeric species comprised of chiral quintuple layers with five decks of linear chains rotated by 120 degrees from level to level, that are perpendicularly joined via five-metal helical motifs; furthermore, each of these two-dimensional frames is catenated by the neighbouring layers to give an overall three-dimensional chiral nanoporous architecture.
Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co-5(bpe)(9)(H2O)(8)(SO4)(4)](SO4)center dot 14H(2)O [bpe=1,2-bis(4-pyridyl)ethane] / L. Carlucci, G. Ciani, D.M. Proserpio, S. Rizzato. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 14(2000), pp. 1319-1320. [10.1039/b002021o]
Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co-5(bpe)(9)(H2O)(8)(SO4)(4)](SO4)center dot 14H(2)O [bpe=1,2-bis(4-pyridyl)ethane]
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioPenultimo
;S. RizzatoUltimo
2000
Abstract
The reaction of cobalt(II) sulfate with 1,2-bis(4-pyridyl)ethane gives a crystalline polymeric species comprised of chiral quintuple layers with five decks of linear chains rotated by 120 degrees from level to level, that are perpendicularly joined via five-metal helical motifs; furthermore, each of these two-dimensional frames is catenated by the neighbouring layers to give an overall three-dimensional chiral nanoporous architecture.File | Dimensione | Formato | |
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