The reaction of cobalt(II) sulfate with 1,2-bis(4-pyridyl)ethane gives a crystalline polymeric species comprised of chiral quintuple layers with five decks of linear chains rotated by 120 degrees from level to level, that are perpendicularly joined via five-metal helical motifs; furthermore, each of these two-dimensional frames is catenated by the neighbouring layers to give an overall three-dimensional chiral nanoporous architecture.

Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co-5(bpe)(9)(H2O)(8)(SO4)(4)](SO4)center dot 14H(2)O [bpe=1,2-bis(4-pyridyl)ethane] / L. Carlucci, G. Ciani, D.M. Proserpio, S. Rizzato. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - :14(2000), pp. 1319-1320.

Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co-5(bpe)(9)(H2O)(8)(SO4)(4)](SO4)center dot 14H(2)O [bpe=1,2-bis(4-pyridyl)ethane]

L. Carlucci
Primo
;
G. Ciani
Secondo
;
D.M. Proserpio
Penultimo
;
S. Rizzato
Ultimo
2000

Abstract

The reaction of cobalt(II) sulfate with 1,2-bis(4-pyridyl)ethane gives a crystalline polymeric species comprised of chiral quintuple layers with five decks of linear chains rotated by 120 degrees from level to level, that are perpendicularly joined via five-metal helical motifs; furthermore, each of these two-dimensional frames is catenated by the neighbouring layers to give an overall three-dimensional chiral nanoporous architecture.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/177381
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