The self-assembly of 1,12-dodecanedinitrile (ddn) with various silver salts (NO3-, PF6-, AsF6-, ClO4-) afforded new polymeric coordination networks with the general formula [Ag(ddn)(2)]X. All these species contain interpenetrating diamondoid nets showing interesting features: with X = NO3 the cationic [Ag(ddn)(2)](+) network exhibits the highest interpenetration (tenfold) ever found within diamondoid nets exclusively based on coordinative bonds. When X=PF6- or AsF6- an eightfold diamondoid network is obtained that shows an unusual [4+4] mode of inter-penetration, instead of the "normal" set of eight nets equally translated along a principal axis of the adamantanoid cages. The polymeric species that forms with X = ClO4- is a fourfold interpenetrating diamondoid network; the lower degree of interpenetration in this case is related to the conformation assumed by the flexible ddn ligands.

Three novel interpenetrating diamondoid networks from self-assembly of 1,12-dodecanedinitrile with silver(I) salts / L. Carlucci, G. Ciani, D.M. Proserpio, S. Rizzato. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 8:7(2002), pp. 1520-1526.

Three novel interpenetrating diamondoid networks from self-assembly of 1,12-dodecanedinitrile with silver(I) salts

L. Carlucci
Primo
;
G. Ciani
Secondo
;
D.M. Proserpio
Penultimo
;
S. Rizzato
Ultimo
2002

Abstract

The self-assembly of 1,12-dodecanedinitrile (ddn) with various silver salts (NO3-, PF6-, AsF6-, ClO4-) afforded new polymeric coordination networks with the general formula [Ag(ddn)(2)]X. All these species contain interpenetrating diamondoid nets showing interesting features: with X = NO3 the cationic [Ag(ddn)(2)](+) network exhibits the highest interpenetration (tenfold) ever found within diamondoid nets exclusively based on coordinative bonds. When X=PF6- or AsF6- an eightfold diamondoid network is obtained that shows an unusual [4+4] mode of inter-penetration, instead of the "normal" set of eight nets equally translated along a principal axis of the adamantanoid cages. The polymeric species that forms with X = ClO4- is a fourfold interpenetrating diamondoid network; the lower degree of interpenetration in this case is related to the conformation assumed by the flexible ddn ligands.
Coordination polymers; Interpenetrating networks; N ligands; Silver
Settore CHIM/03 - Chimica Generale e Inorganica
Article (author)
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/177371
Citazioni
  • ???jsp.display-item.citation.pmc??? 2
  • Scopus 102
  • ???jsp.display-item.citation.isi??? 210
social impact