Bicyclo[5.3.1]undec-1(10)-en-9-one undergoes photodeconjugation to give bicyclo[5.3.1]undec-1(2)-en-9-one, which, in turn is transformed into the corresponding methylenebicyclo[4.2.2]decanone. The non-volatile fraction of the photolysate is shown to be a mixture of cyclobutane-type dimeric derivatives.
Photochemical behaviour of bicyclo[5.3.1]undec-1(10)-en-9-one / B. Gioia, M. Ballabio, E.M. Beccalli, R. Cecchi, A. Marchesini. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - 2(1981), pp. 560-564. [10.1039/P19810000560]
Photochemical behaviour of bicyclo[5.3.1]undec-1(10)-en-9-one
E.M. Beccalli;A. MarchesiniUltimo
1981
Abstract
Bicyclo[5.3.1]undec-1(10)-en-9-one undergoes photodeconjugation to give bicyclo[5.3.1]undec-1(2)-en-9-one, which, in turn is transformed into the corresponding methylenebicyclo[4.2.2]decanone. The non-volatile fraction of the photolysate is shown to be a mixture of cyclobutane-type dimeric derivatives.
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