Several low loading supported catalysts were tested in the hydrogen transfer reduction of 4-tert-butyl-cyclohexanone showing good activity under very mild conditions (2-propanol as solvent, 83 C, N2). Results obtained by using different alcohols as donors suggest that a two step dehydrogenation-hydrogenation mechanism is operating over Cu/SiO2.
|Titolo:||The use of copper catalysts in the hydrogen transfer reduction of 4-tert-butylcyclohexanone|
|Autori interni:||FUSI, ACHILLE (Secondo)|
ZACCHERIA, FEDERICA (Primo)
|Settore Scientifico Disciplinare:||Settore CHIM/03 - Chimica Generale e Inorganica|
|Data di pubblicazione:||2005|
|Tipologia:||Book Part (author)|
|Appare nelle tipologie:||03 - Contributo in volume|