The std. emf. was detd. in a reversible cell e.g. Pt|H2 (1 atm.)|KHPh + KCl(aq. solvent)|AgCl|Ag|Pt where KHPh = K acid phthalate. Detns. were made in 0 to 70 wt. % EtOH/H2O solns. Also, std. thermodn. functions, ΔG°, ΔH°, ΔS° and ΔC° were calcd. for some of the EtOH/H2O solns. Also, the mean molal activity coeffs. for HCl at various temps. and molalities in the 70:30 alc./H2O soln. were detd.

Influence of ion-size parameter selection on determinations of standard electromotive force for the hydrogen/silver-chloride cell in ethanol/water solvent mixtures / S. Rondinini, P. Longhi, P.R. Mussini, T. Mussini. - In: LA CHIMICA E L'INDUSTRIA. - ISSN 0009-4315. - 70:6(1988), pp. 93-97.

Influence of ion-size parameter selection on determinations of standard electromotive force for the hydrogen/silver-chloride cell in ethanol/water solvent mixtures

S. Rondinini
Primo
;
P. Longhi
Secondo
;
P.R. Mussini
Penultimo
;
T. Mussini
Ultimo
1988

Abstract

The std. emf. was detd. in a reversible cell e.g. Pt|H2 (1 atm.)|KHPh + KCl(aq. solvent)|AgCl|Ag|Pt where KHPh = K acid phthalate. Detns. were made in 0 to 70 wt. % EtOH/H2O solns. Also, std. thermodn. functions, ΔG°, ΔH°, ΔS° and ΔC° were calcd. for some of the EtOH/H2O solns. Also, the mean molal activity coeffs. for HCl at various temps. and molalities in the 70:30 alc./H2O soln. were detd.
Settore CHIM/01 - Chimica Analitica
Settore CHIM/02 - Chimica Fisica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/176377
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