A novel electrochem. method of synthesizing aryl-O-glycosides by cathodic redn. of glycosyl halides has been developed and applied to a set of phenols and polyhydroxyphenols as std. aglycons. The encouraging yields and the product stereospecificity point out to a promising application field.
Diastereoselective synthesis of aryl O-glycosides by electrochemical reduction of glycosyl halides / M. Benedetto, G. Miglierini, P.R. Mussini, F. Pelizzoni, S. Rondinini, G. Sello. - In: CARBOHYDRATE LETTERS. - ISSN 1073-5070. - 1:5(1995), pp. 321-328.
Diastereoselective synthesis of aryl O-glycosides by electrochemical reduction of glycosyl halides
P.R. Mussini;F. Pelizzoni;S. RondininiPenultimo
;G. SelloUltimo
1995
Abstract
A novel electrochem. method of synthesizing aryl-O-glycosides by cathodic redn. of glycosyl halides has been developed and applied to a set of phenols and polyhydroxyphenols as std. aglycons. The encouraging yields and the product stereospecificity point out to a promising application field.
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