2-O-β-D-glucopyranosylglycerol was submitted to acylation using Pseudomonas cepacia lipase as catalyst and 2,2,2-trifluoroethyl esters of various long chain carboxylic acids as acyl carriers. Monoacylation was easily accomplished with preferred formation of the (2S)-1-O-acyl derivatives in reactions showing high regio- and diastereoselectivity.

A facile lipase catalyzed access to fatty acid monoesters of 2-O-beta-D-glucosylglycerol / D. Colombo, F. Ronchetti, A. Scala, I. Taino, L. Toma. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 7:3(1996), pp. 771-777. [10.1016/0957-4166(96)00073-0]

A facile lipase catalyzed access to fatty acid monoesters of 2-O-beta-D-glucosylglycerol

D. Colombo
Primo
;
F. Ronchetti
Secondo
;
A. Scala;
1996

Abstract

2-O-β-D-glucopyranosylglycerol was submitted to acylation using Pseudomonas cepacia lipase as catalyst and 2,2,2-trifluoroethyl esters of various long chain carboxylic acids as acyl carriers. Monoacylation was easily accomplished with preferred formation of the (2S)-1-O-acyl derivatives in reactions showing high regio- and diastereoselectivity.
Settore BIO/10 - Biochimica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/175805
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