The Pseudomonas cepacia lipase selectively catalyzes the acylation of the (20S)-isomer of the 22-alcohol group in the C-22 steroid compounds 1a and 4a when the transesterification is irreversibly carried out with vinyl acetate in an organic solvent. (C) 1996 Elsevier Science Ltd
The first example of lipase-catalyzed resolution of a stereogenic center in steroid side chains by transesterification in organic solvent / P. Ferraboschi, A. Molatore, E. Verza, E. Santaniello. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 7:6(1996), pp. 1551-1554. [10.1016/0957-4166(96)00178-4]
The first example of lipase-catalyzed resolution of a stereogenic center in steroid side chains by transesterification in organic solvent
P. FerraboschiPrimo
;E. SantanielloUltimo
1996
Abstract
The Pseudomonas cepacia lipase selectively catalyzes the acylation of the (20S)-isomer of the 22-alcohol group in the C-22 steroid compounds 1a and 4a when the transesterification is irreversibly carried out with vinyl acetate in an organic solvent. (C) 1996 Elsevier Science Ltd
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