The Pseudomonas cepacia lipase selectively catalyzes the acylation of the (20S)-isomer of the 22-alcohol group in the C-22 steroid compounds 1a and 4a when the transesterification is irreversibly carried out with vinyl acetate in an organic solvent. (C) 1996 Elsevier Science Ltd

The first example of lipase-catalyzed resolution of a stereogenic center in steroid side chains by transesterification in organic solvent / P. Ferraboschi, A. Molatore, E. Verza, E. Santaniello. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 7:6(1996), pp. 1551-1554. [10.1016/0957-4166(96)00178-4]

The first example of lipase-catalyzed resolution of a stereogenic center in steroid side chains by transesterification in organic solvent

P. Ferraboschi
Primo
;
E. Santaniello
Ultimo
1996

Abstract

The Pseudomonas cepacia lipase selectively catalyzes the acylation of the (20S)-isomer of the 22-alcohol group in the C-22 steroid compounds 1a and 4a when the transesterification is irreversibly carried out with vinyl acetate in an organic solvent. (C) 1996 Elsevier Science Ltd
Settore BIO/10 - Biochimica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/175795
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