The glycosylation with trichloroacetimidates derived from different glycopyranoses bearing a nonparticipating group at C-2 was explored in different ionic liquids as solvents. The stereoselectivity of the reaction was significantly affected by the reaction media and by the anomeric configuration of the donor.
Glycosylation with trichloroacetimidates in ionic liquids: influence of the reaction medium on the stereochemical outcome / L. Poletti, A. Rencurosi, L. Lay, G. Russo. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 70:19(2005), pp. 7765-7768. ((Intervento presentato al 1. convegno International congress on ionic liquids tenutosi a Salzburg nel 2005.
Glycosylation with trichloroacetimidates in ionic liquids: influence of the reaction medium on the stereochemical outcome
L. Poletti
;L. LayPenultimo
;G. RussoUltimo
2005
Abstract
The glycosylation with trichloroacetimidates derived from different glycopyranoses bearing a nonparticipating group at C-2 was explored in different ionic liquids as solvents. The stereoselectivity of the reaction was significantly affected by the reaction media and by the anomeric configuration of the donor.
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