The Pseudomonas fluorescens (P. cepacia) lipase-catalyzed irreversible transesterification of 2-phenyl-1,2-propanediol 1a is not enantioselective, whereas the diols 1b and 1c are enzymatically resolved with the same procedure to (S)-1b and 1c (>98 and 92% e.e.) and the (R)-acetates 2b and 2c (92% e.e.).
Enantioselective Pseudomonas fluorescens (P. cepacia) lipase-catalyzed irreversible transesterification of 2-methyl-1,2-diols in an organic solvent / P. Ferraboschi, S. Casati, P. Grisenti, E. Santaniello. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 5:10(1994), pp. 1921-1924. [10.1016/S0957-4166(00)86267-9]
Enantioselective Pseudomonas fluorescens (P. cepacia) lipase-catalyzed irreversible transesterification of 2-methyl-1,2-diols in an organic solvent
P. FerraboschiPrimo
;S. CasatiSecondo
;E. SantanielloUltimo
1994
Abstract
The Pseudomonas fluorescens (P. cepacia) lipase-catalyzed irreversible transesterification of 2-phenyl-1,2-propanediol 1a is not enantioselective, whereas the diols 1b and 1c are enzymatically resolved with the same procedure to (S)-1b and 1c (>98 and 92% e.e.) and the (R)-acetates 2b and 2c (92% e.e.).
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