The regioselectivity of the Pseudomonas fluorescens (P. cepacia) lipase (PFL)-catalyzed irreversible transesterification of 2-substituted-1,4-butanediols 1a-3a has been studied and, in the case of 3a, it has been shown that (R)- and (S)-diols are acylated with opposite regioselectivity.
Regio- and enantioselective properties of the lipase-catalyzed irreversible transesterification of some 2-substituted-1,4-butanediols in organic solvents / P. Ferraboschi, S. Casati, E. Verza, E. Santaniello. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 6:5(1995), pp. 1027-1030. [10.1016/0957-4166(95)00116-7]
Regio- and enantioselective properties of the lipase-catalyzed irreversible transesterification of some 2-substituted-1,4-butanediols in organic solvents
P. FerraboschiPrimo
;S. CasatiSecondo
;E. SantanielloUltimo
1995
Abstract
The regioselectivity of the Pseudomonas fluorescens (P. cepacia) lipase (PFL)-catalyzed irreversible transesterification of 2-substituted-1,4-butanediols 1a-3a has been studied and, in the case of 3a, it has been shown that (R)- and (S)-diols are acylated with opposite regioselectivity.
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