Ion-transfer parameters of aq. hydrochloric acid over a wide molality range have been re-investigated taking the concurrent solvent-transfer into due account. In this context, the transference nos. for the hydrogen ion τH and for water τw have been detd. from 10-2 to 15 mol-kg-1, together with the corresponding infinite-diln. values τH0×w0, by processing a set of nearly a hundred emf. measurements (some twenty of them new for this work) on HCl concn. cells with transference with both cation-reversible and anion- reversible electrode pairs.
Transference numbers of aqueous HCl up to 15 mol-kg-1 at 25°C : a systematization and reassessment / P. Longhi, P.R. Mussini, G. Perboni, S. Rondinini. - In: JOURNAL OF SOLUTION CHEMISTRY. - ISSN 0095-9782. - 24:4(1995), pp. 311-324.
Transference numbers of aqueous HCl up to 15 mol-kg-1 at 25°C : a systematization and reassessment
P. LonghiPrimo
;P.R. MussiniSecondo
;S. RondininiUltimo
1995
Abstract
Ion-transfer parameters of aq. hydrochloric acid over a wide molality range have been re-investigated taking the concurrent solvent-transfer into due account. In this context, the transference nos. for the hydrogen ion τH and for water τw have been detd. from 10-2 to 15 mol-kg-1, together with the corresponding infinite-diln. values τH0×w0, by processing a set of nearly a hundred emf. measurements (some twenty of them new for this work) on HCl concn. cells with transference with both cation-reversible and anion- reversible electrode pairs.Pubblicazioni consigliate
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