The absolute rate constants for the addition of alkyl radicals to styrene and acrylic monomers are determined by two kinetic models. The first evaluates the ratio of electron-transfer oxidation by copper(II) acetate and addition to the double bonds, and the second determines the relative rates of alternating addition to acrylic monomers. The results are compared with the values in gas-phase reactions and are discussed in terms of polar effects and frontier orbital theory. The synthetic interest of the reactions involved is emphasized.

Nucleophilic character of alkyl radicals. Part 17. Absolute rate constants and the alternating effect in the addition of alkyl radicals to styrene and acrylic monomers / A. Citterio, F. Minisci, A. Arnoldi, R. Pagano, A. Parravicini, O. Porta. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS 2. - ISSN 1472-779X. - 1978:2(1978), pp. 519-524. [10.1039/P29780000519]

Nucleophilic character of alkyl radicals. Part 17. Absolute rate constants and the alternating effect in the addition of alkyl radicals to styrene and acrylic monomers

A. Arnoldi;
1978

Abstract

The absolute rate constants for the addition of alkyl radicals to styrene and acrylic monomers are determined by two kinetic models. The first evaluates the ratio of electron-transfer oxidation by copper(II) acetate and addition to the double bonds, and the second determines the relative rates of alternating addition to acrylic monomers. The results are compared with the values in gas-phase reactions and are discussed in terms of polar effects and frontier orbital theory. The synthetic interest of the reactions involved is emphasized.
English
Settore CHIM/06 - Chimica Organica
Articolo
Esperti anonimi
1978
1978
2
519
524
Pubblicato
Periodico con rilevanza internazionale
info:eu-repo/semantics/article
Nucleophilic character of alkyl radicals. Part 17. Absolute rate constants and the alternating effect in the addition of alkyl radicals to styrene and acrylic monomers / A. Citterio, F. Minisci, A. Arnoldi, R. Pagano, A. Parravicini, O. Porta. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS 2. - ISSN 1472-779X. - 1978:2(1978), pp. 519-524. [10.1039/P29780000519]
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262
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Periodico senza Impact Factor
A. Citterio, F. Minisci, A. Arnoldi, R. Pagano, A. Parravicini, O. Porta
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/175291
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