A review with 29 refs. The international conventions and procedures concerning the pH-metric and pIon-metric detns. are critically discussed and key factors affecting the reliability of such detns. are analyzed: sensing and ref. electrodes, salt bridges, ref. value and primary stds., influence quantities, intercomparability circumstances for different pH and pIon scales, basic phys.-chem. and electrochem. concepts of the IUPAC standardization schemes, and predictability of new stds. in yet unexplored solvents.
Standardization and conditions for reliability of pH and pIon determinations / E. Dolbniak Leonowicz, P.R. Mussini, T. Mussini, S. Rondinini, B. Szmagier. - In: CHEMIA ANALITYCZNA. - ISSN 0009-2223. - 39:1(1994), pp. 13-27.
Standardization and conditions for reliability of pH and pIon determinations
P.R. MussiniSecondo
;T. Mussini;S. RondininiPenultimo
;
1994
Abstract
A review with 29 refs. The international conventions and procedures concerning the pH-metric and pIon-metric detns. are critically discussed and key factors affecting the reliability of such detns. are analyzed: sensing and ref. electrodes, salt bridges, ref. value and primary stds., influence quantities, intercomparability circumstances for different pH and pIon scales, basic phys.-chem. and electrochem. concepts of the IUPAC standardization schemes, and predictability of new stds. in yet unexplored solvents.
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