Recent transference-cell e.m.f. data sets for various 1:1 electrolytes in aqueous-organic solvent mixtures obtained in these laboratories for the determination of ionic transference numbers have been aggregated with earlier sets for 1:1 electrolytes in aqueous solutions and reexamined in the light of a new theoretical approach accounting for the solvent transfer phenomena accompanying ionic transfer. The potentialities and the precision of the transference-cell e.m.f. method have been highlighted, and new salt bridges, for use in aqueous-organic solvents, have been thereby characterized.
Recent advances in the electromotive force method for determining transference numbers of electrolytes and characterizing new salt bridges / P.R. Mussini, T. Mussini. - In: JOURNAL OF APPLIED ELECTROCHEMISTRY. - ISSN 0021-891X. - 28:12(1998 Dec), pp. 1305-1311.
Recent advances in the electromotive force method for determining transference numbers of electrolytes and characterizing new salt bridges
P.R. MussiniPrimo
;T. MussiniUltimo
1998
Abstract
Recent transference-cell e.m.f. data sets for various 1:1 electrolytes in aqueous-organic solvent mixtures obtained in these laboratories for the determination of ionic transference numbers have been aggregated with earlier sets for 1:1 electrolytes in aqueous solutions and reexamined in the light of a new theoretical approach accounting for the solvent transfer phenomena accompanying ionic transfer. The potentialities and the precision of the transference-cell e.m.f. method have been highlighted, and new salt bridges, for use in aqueous-organic solvents, have been thereby characterized.Pubblicazioni consigliate
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