The electrochem. redn. of α-D-glycopyranosyl bromides has been investigated both by cyclic voltammetry and const. potential electrolysis on a mercury cathode. In the presence of suitable radical acceptors such as acrylonitrile or resorcinol, the intermediate glycosyl radical formed during the first redn. step can react with formation of a CC or CO bond on the anomeric carbon. The reaction products of preliminary explorative electrolysis were isolated and characterized.
Electrochemical reduction of α-D-glycopyranosyl bromides on a mercury cathode / S. Rondinini, P.R. Mussini, V. Ferzetti, D. Monti. - In: ELECTROCHIMICA ACTA. - ISSN 0013-4686. - 36:5-6(1991), pp. 1095-1098.
Electrochemical reduction of α-D-glycopyranosyl bromides on a mercury cathode
S. RondininiPrimo
;P.R. MussiniSecondo
;
1991
Abstract
The electrochem. redn. of α-D-glycopyranosyl bromides has been investigated both by cyclic voltammetry and const. potential electrolysis on a mercury cathode. In the presence of suitable radical acceptors such as acrylonitrile or resorcinol, the intermediate glycosyl radical formed during the first redn. step can react with formation of a CC or CO bond on the anomeric carbon. The reaction products of preliminary explorative electrolysis were isolated and characterized.
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