The original data of emf. of the cell H2|HCl|AgCl|Ag as measured by different schools at various HCl molalities in up to 50 wt.% EtOH/H2O, at normal and subzero temps. (263 to 313 K) were analyzed by a recently described, single-stage, multilinear regression method. The best values of std. emf. E° of the cell, which are key quantities for the acquisition of the ref. value stds. of pH in the above solvent mixts., were detd. together with the fundamental thermodn. functions ΔG°, ΔH° and ΔS° for the cell reaction.
A re-examination of the standard electromotive force of the hydrogen/silver chloride cell in ethanol/water solvent mixtures at various temperatures / P.R. Mussini, T. Mussini, S. Rondinini. - In: ANNALI DI CHIMICA. - ISSN 0003-4592. - 76:9-10(1986), pp. 333-343.
Titolo: | A re-examination of the standard electromotive force of the hydrogen/silver chloride cell in ethanol/water solvent mixtures at various temperatures |
Autori: | MUSSINI, PATRIZIA ROMANA (Primo) MUSSINI, TORQUATO (Secondo) RONDININI, SANDRA (Ultimo) |
Settore Scientifico Disciplinare: | Settore CHIM/01 - Chimica Analitica Settore CHIM/02 - Chimica Fisica |
Data di pubblicazione: | 1986 |
Rivista: | |
Tipologia: | Article (author) |
Appare nelle tipologie: | 01 - Articolo su periodico |