Lost in solvation: A study of the basicity of (2,6-pyridino)paracyclophanes (see picture; C light blue, N blue, S orange, F yellow, H green) reveals the importance of bulk solvation compared to cation-π effects in determining the relative stability of cations.
Basicity of (2,6-pyridino)paracyclophanes : lone pair-pi, cation-pi, and solvation effects / K.K. Baldridge, F. Cozzi, J.S. Siegel. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 51:12(2012 Mar 19), pp. 2903-2906.
Basicity of (2,6-pyridino)paracyclophanes : lone pair-pi, cation-pi, and solvation effects
F. CozziSecondo
;
2012
Abstract
Lost in solvation: A study of the basicity of (2,6-pyridino)paracyclophanes (see picture; C light blue, N blue, S orange, F yellow, H green) reveals the importance of bulk solvation compared to cation-π effects in determining the relative stability of cations.
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