Lost in solvation: A study of the basicity of (2,6-pyridino)paracyclophanes (see picture; C light blue, N blue, S orange, F yellow, H green) reveals the importance of bulk solvation compared to cation-π effects in determining the relative stability of cations.
Basicity of (2,6-pyridino)paracyclophanes : lone pair-pi, cation-pi, and solvation effects / K.K. Baldridge, F. Cozzi, J.S. Siegel. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 51:12(2012 Mar 19), pp. 2903-2906.
Titolo: | Basicity of (2,6-pyridino)paracyclophanes : lone pair-pi, cation-pi, and solvation effects |
Autori: | COZZI, FRANCO (Secondo) |
Parole Chiave: | π interactions; basicity; cations; cyclophanes; solvent effects |
Settore Scientifico Disciplinare: | Settore CHIM/06 - Chimica Organica |
Data di pubblicazione: | 19-mar-2012 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/anie.201108545 |
Appare nelle tipologie: | 01 - Articolo su periodico |
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