A novel stereoselective synthesis of carba-L-rhamnose from (-)-quinic acid is described. The title compound is obtained with an appropriate pattern of protecting groups to be used for the preparation of Streptococcus pneumoniae type 19F capsular polysaccharide repeating unit.
An Efficient Transformation of (-)-Quinic Acid into Carba-L-Rhamnose / E. Valsecchi, A. Tacchi, D. Prosperi, F. Compostella, L. Panza. - In: SYNLETT. - ISSN 0936-5214. - 14:14(2004), pp. 2529-2532. [10.1055/s-2004-834825]
An Efficient Transformation of (-)-Quinic Acid into Carba-L-Rhamnose
F. CompostellaPenultimo
;
2004
Abstract
A novel stereoselective synthesis of carba-L-rhamnose from (-)-quinic acid is described. The title compound is obtained with an appropriate pattern of protecting groups to be used for the preparation of Streptococcus pneumoniae type 19F capsular polysaccharide repeating unit.
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