The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)].H2O (L1 = N,N'-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4-benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)].2H2O, 2, and [Zn2(L2)(1,4-BDC)2].2CH3OH (L2 = N,N'-di(4-pyridyl)dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.
Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands / J.-J. Cheng, Y.-T. Chang, C.-J. Wu, Y.-F. Hsu, C.-H. Lin, D.M. Proserpio, J.-D. Chen. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 14:2(2012), pp. 537-543. [10.1039/c1ce06019h]
Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands
D.M. ProserpioPenultimo
;
2012
Abstract
The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)].H2O (L1 = N,N'-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4-benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)].2H2O, 2, and [Zn2(L2)(1,4-BDC)2].2CH3OH (L2 = N,N'-di(4-pyridyl)dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.File | Dimensione | Formato | |
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