Phosphorus acids are excellent promoters for the palladium-phenanthroline catalyzed corbonylation of 2,4-dinitrotoluene to 2,4-toluenedicarbamate. For the first time, all intermediate nitrocarbamates and aminocarbamates have been independently synthesized and their amount after every catalytic reaction precisely quantified.
Carbonylation of dinitrotoluene to dimethyl toluenedicarbamate; high efficiency of phosphorus acids as promoters for the palladium-phenanthroline catalytic system / M. Gasperini, F. Ragaini, C. Cazzaniga, S. Cenini. - In: ADVANCED SYNTHESIS & CATALYSIS. - ISSN 1615-4150. - 347:1(2005), pp. 105-120.
Carbonylation of dinitrotoluene to dimethyl toluenedicarbamate; high efficiency of phosphorus acids as promoters for the palladium-phenanthroline catalytic system
F. RagainiSecondo
;S. CeniniUltimo
2005
Abstract
Phosphorus acids are excellent promoters for the palladium-phenanthroline catalyzed corbonylation of 2,4-dinitrotoluene to 2,4-toluenedicarbamate. For the first time, all intermediate nitrocarbamates and aminocarbamates have been independently synthesized and their amount after every catalytic reaction precisely quantified.
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