The reaction of Ru(TPP)CO (TPP = dianion of tetraphenylporphyrin) with 1-(p-nitrophenyl)-5-methyl-5-phenyl- 1,2,3-triazoline yielded a Delta(2)-1,2,3-triazoline ruthenium(II) porphyrin complex, which is responsible for the catalyst deactivation in the aziridination reaction of (x-methylstyrene by p-nitrophenyl azide.
Origin of the deactivation in styrene aziridination by aryl azides, catalyzed by ruthenium porphyrin complexes. Structural characterization of a Delta(2)-1,2,3-triazoline Ru-II(TPP)CO complex / S. Fantauzzi, E. Gallo, A. Caselli, F. Ragaini, P. Macchi, N. Casati, S. Cenini. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 24:20(2005), pp. 4710-4713. [10.1021/om050244y]
Origin of the deactivation in styrene aziridination by aryl azides, catalyzed by ruthenium porphyrin complexes. Structural characterization of a Delta(2)-1,2,3-triazoline Ru-II(TPP)CO complex
S. FantauzziPrimo
;E. GalloSecondo
;A. Caselli;F. Ragaini;P. Macchi;S. CeniniUltimo
2005
Abstract
The reaction of Ru(TPP)CO (TPP = dianion of tetraphenylporphyrin) with 1-(p-nitrophenyl)-5-methyl-5-phenyl- 1,2,3-triazoline yielded a Delta(2)-1,2,3-triazoline ruthenium(II) porphyrin complex, which is responsible for the catalyst deactivation in the aziridination reaction of (x-methylstyrene by p-nitrophenyl azide.
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