The nucleophilic reactivity of a homogeneous series of anions (halides, pseudohalides and organic anions) in the ionic liquids [hexmim] [ClO4] and [hexmim] [PF6] has been measured in their reaction with n-alkyl methanesulfonates, and compared with that found in traditional molecular solvents of different polarity, that is, chlorobenzene, DMSO, and MeOH. (c) 2005 Elsevier Ltd. All rights reserved.

Anion nucleophilicity in ionic liquids: a comparison with traditional molecular solvents of different polarity / D. Landini, A. Maia. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 46:23(2005), pp. 3961-3963.

Anion nucleophilicity in ionic liquids: a comparison with traditional molecular solvents of different polarity

D. Landini
Primo
;
2005

Abstract

The nucleophilic reactivity of a homogeneous series of anions (halides, pseudohalides and organic anions) in the ionic liquids [hexmim] [ClO4] and [hexmim] [PF6] has been measured in their reaction with n-alkyl methanesulfonates, and compared with that found in traditional molecular solvents of different polarity, that is, chlorobenzene, DMSO, and MeOH. (c) 2005 Elsevier Ltd. All rights reserved.
nucleophilic substitutions; anion reactivity; ionic liquids; hydrogen bonding effect; water effect
Settore CHIM/04 - Chimica Industriale
2005
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/16306
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