The nucleophilic reactivity of a homogeneous series of anions (halides, pseudohalides and organic anions) in the ionic liquids [hexmim] [ClO4] and [hexmim] [PF6] has been measured in their reaction with n-alkyl methanesulfonates, and compared with that found in traditional molecular solvents of different polarity, that is, chlorobenzene, DMSO, and MeOH. (c) 2005 Elsevier Ltd. All rights reserved.
Anion nucleophilicity in ionic liquids: a comparison with traditional molecular solvents of different polarity / D. Landini, A. Maia. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 46:23(2005), pp. 3961-3963.
Anion nucleophilicity in ionic liquids: a comparison with traditional molecular solvents of different polarity
D. LandiniPrimo
;
2005
Abstract
The nucleophilic reactivity of a homogeneous series of anions (halides, pseudohalides and organic anions) in the ionic liquids [hexmim] [ClO4] and [hexmim] [PF6] has been measured in their reaction with n-alkyl methanesulfonates, and compared with that found in traditional molecular solvents of different polarity, that is, chlorobenzene, DMSO, and MeOH. (c) 2005 Elsevier Ltd. All rights reserved.
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