The title reaction, a set of concurrent-consecutive steps, was studied in a slurry batch reactor at 50, 65, and 75 degrees C, using cyclohexane as solvent and Nafion SAC-13 as solid acid catalyst. The final products were found to be dibenzylether, the isomers of benzyltoluene and dibenzyltoluenes and small amounts of unidentified byproducts. The kinetic results were interpreted by a Langmuir-Hinshelwood model, evaluating the main kinetics and adsorption coefficient involved in the reactions and their temperature dependence. (c) 2004 Elsevier B.V. All rights reserved.
Kinetics of the reaction of toluene with benzyl alcohol over a Nafion-silica composite / P. Beltrame, G. Zuretti. - In: APPLIED CATALYSIS A: GENERAL. - ISSN 0926-860X. - 283:1-2(2005), pp. 33-38. [10.1016/j.apcata.2004.12.031]
Kinetics of the reaction of toluene with benzyl alcohol over a Nafion-silica composite
P. BeltramePrimo
;
2005
Abstract
The title reaction, a set of concurrent-consecutive steps, was studied in a slurry batch reactor at 50, 65, and 75 degrees C, using cyclohexane as solvent and Nafion SAC-13 as solid acid catalyst. The final products were found to be dibenzylether, the isomers of benzyltoluene and dibenzyltoluenes and small amounts of unidentified byproducts. The kinetic results were interpreted by a Langmuir-Hinshelwood model, evaluating the main kinetics and adsorption coefficient involved in the reactions and their temperature dependence. (c) 2004 Elsevier B.V. All rights reserved.
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