7-N,N-Dibutylamino-2-azaphenanthrene (L-3), 8-N,N-dibutylamino-2-azachrysene (L-4) and related Ir(I) complexes or alkylated salts show high second-order NLO responses, as determined by the EFISH technique and DFT calculations. L-4 is appealing as building block for NLO active materials due to its unexpected large mu beta(1.907)value and its very high thermal stability.

Highly stable 7-N,N-dibutylamino-2-azaphenanthrene and 8-N,N-dibutylamino-2-azachrysene as a new class of second order NLO-active chromophores / V. Calabrese, S. Quici, E. Rossi, E. Cariati, C. Dragonetti, D.M. Roberto, E. Tordin, F. De Angelis, S. Fantacci. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 46:44(2010), pp. 8374-8376. [10.1039/c0cc02781b]

Highly stable 7-N,N-dibutylamino-2-azaphenanthrene and 8-N,N-dibutylamino-2-azachrysene as a new class of second order NLO-active chromophores

V. Calabrese;E. Rossi;E. Cariati;C. Dragonetti;D.M. Roberto;E. Tordin;
2010

Abstract

7-N,N-Dibutylamino-2-azaphenanthrene (L-3), 8-N,N-dibutylamino-2-azachrysene (L-4) and related Ir(I) complexes or alkylated salts show high second-order NLO responses, as determined by the EFISH technique and DFT calculations. L-4 is appealing as building block for NLO active materials due to its unexpected large mu beta(1.907)value and its very high thermal stability.
Settore CHIM/03 - Chimica Generale e Inorganica
2010
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/154742
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