7-N,N-Dibutylamino-2-azaphenanthrene (L-3), 8-N,N-dibutylamino-2-azachrysene (L-4) and related Ir(I) complexes or alkylated salts show high second-order NLO responses, as determined by the EFISH technique and DFT calculations. L-4 is appealing as building block for NLO active materials due to its unexpected large mu beta(1.907)value and its very high thermal stability.
Highly stable 7-N,N-dibutylamino-2-azaphenanthrene and 8-N,N-dibutylamino-2-azachrysene as a new class of second order NLO-active chromophores / V. Calabrese, S. Quici, E. Rossi, E. Cariati, C. Dragonetti, D.M. Roberto, E. Tordin, F. De Angelis, S. Fantacci. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 46:44(2010), pp. 8374-8376. [10.1039/c0cc02781b]
Highly stable 7-N,N-dibutylamino-2-azaphenanthrene and 8-N,N-dibutylamino-2-azachrysene as a new class of second order NLO-active chromophores
V. Calabrese;E. Rossi;E. Cariati;C. Dragonetti;D.M. Roberto;E. Tordin;
2010
Abstract
7-N,N-Dibutylamino-2-azaphenanthrene (L-3), 8-N,N-dibutylamino-2-azachrysene (L-4) and related Ir(I) complexes or alkylated salts show high second-order NLO responses, as determined by the EFISH technique and DFT calculations. L-4 is appealing as building block for NLO active materials due to its unexpected large mu beta(1.907)value and its very high thermal stability.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
