A new dinuclear Ru(II) complex where two Ru atoms are separated by a bridge consisting of a 2,1,3-benzothiadiazole acceptor moiety flanked on either side by 2,5-thienyl donor units was synthesized. This rather simple complex appears to behave as a photoactive donor when blended with a fullerene as acceptor, thus being a first step toward novel bulk heterojunction solar cells, based on Ru donor systems.
A Novel Diruthenium Acetylide Donor Complex as an Unusual Active Material for Bulk Heterojunction Solar Cells / A. Colombo, C. Dragonetti, D.M. Roberto, R. Ugo, L. Falciola, S. Luzzati, D. Kotowski. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 30:6(2011 Mar), pp. 1279-1282.
A Novel Diruthenium Acetylide Donor Complex as an Unusual Active Material for Bulk Heterojunction Solar Cells
A. Colombo;C. Dragonetti;D.M. Roberto;R. Ugo;L. Falciola;
2011
Abstract
A new dinuclear Ru(II) complex where two Ru atoms are separated by a bridge consisting of a 2,1,3-benzothiadiazole acceptor moiety flanked on either side by 2,5-thienyl donor units was synthesized. This rather simple complex appears to behave as a photoactive donor when blended with a fullerene as acceptor, thus being a first step toward novel bulk heterojunction solar cells, based on Ru donor systems.
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