The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.
The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar=3,5-(CF3)(2)C6H3) / S.M. Fantauzzi, E. Gallo, A. Caselli, F.A.C. Ragaini, N. Casati, P. Macchi, S. Cenini. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 2009:26(2009), pp. 3952-3954.
The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar=3,5-(CF3)(2)C6H3)
S.M. FantauzziPrimo
;E. GalloSecondo
;A. Caselli;F.A.C. Ragaini;P. MacchiPenultimo
;S. CeniniUltimo
2009
Abstract
The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.
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