The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.

The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar=3,5-(CF3)(2)C6H3) / S.M. Fantauzzi, E. Gallo, A. Caselli, F.A.C. Ragaini, N. Casati, P. Macchi, S. Cenini. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 2009:26(2009), pp. 3952-3954.

The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar=3,5-(CF3)(2)C6H3)

S. M. Fantauzzi;E. Gallo;A. Caselli;F. A. C. Ragaini;P. Macchi;S. Cenini
2009

Abstract

The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.
Transition-metal-complexes; hydrogen-atom transfer; ruthenium porphyrins; manganese-porphyrins; aryl azides; intramolecular amidation; aziridination; hydrocarbons; functionalization; activation
Settore CHIM/03 - Chimica Generale e Inorganica
CHEMICAL COMMUNICATIONS
Article (author)
File in questo prodotto:
File Dimensione Formato  
47) Ru-immido.pdf

non disponibili

581.37 kB Adobe PDF   Visualizza/Apri   Richiedi una copia
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/147379
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 93
  • ???jsp.display-item.citation.isi??? 92
social impact