Fe-Cu octahedral carbide clusters and the replacement of their labile halide ligands: Synthesis, solid state structure, substitution and electrochemnical reactivity of [Fe5C(CO)14(CuBr)]2-,[Fe4C(CO)12(CuCl)2]2-, è(Fe4Cu2C(CO)12(mu-Cl))2]2-, [Fe5C(CO)14(CuOC4H8)]- and [Fe4C(CO)12[CuNCMe)2]