Recent progress, with some emphasis on the author’s own work, on the understanding of the mechanism of the reductive carbonylation of nitroarenes and of the oxidative carbonylation of amines is discussed, highlighting the close connection between the two reactions and trying to unify scattered data in the literature. Isocyanates, carbamates and ureas can be obtained by either procedure, without the need for the use of the toxic and corrosive phosgene
Away from Phosgene : Reductive Carbonylation of Nitroarenes and Oxidative Carbonylation of Amines, Understanding the Mechanism to Improve Performance / F. A. C. Ragaini. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - :32(2009), pp. 6251-6266.
Away from Phosgene : Reductive Carbonylation of Nitroarenes and Oxidative Carbonylation of Amines, Understanding the Mechanism to Improve Performance
F. A. C. RagainiPrimo
2009
Abstract
Recent progress, with some emphasis on the author’s own work, on the understanding of the mechanism of the reductive carbonylation of nitroarenes and of the oxidative carbonylation of amines is discussed, highlighting the close connection between the two reactions and trying to unify scattered data in the literature. Isocyanates, carbamates and ureas can be obtained by either procedure, without the need for the use of the toxic and corrosive phosgene
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