Tetrairidium carbonyl clusters are potentially useful connectors for multidimensional functionalized frameworks with organic bis-phosphines as linkers. The reaction of Ir4(CO)12 and 1,4-bis(diphenylphosphinomethyl)benzene produces an oligomeric cyclic structure, made of 4 connectors and 6 linkers, a possible intermediate in the formation of three dimensional networks.
Four tetrairidium carbonyl clusters linked by six diphosphino ligands : synthesis and X-ray structure of [{Ir4(CO)9}4(dppmb)6] (dppmb = 1,4-bis(diphenylphosphinomethyl)benzene / G. Peli, M.A.A. Daghetta, P. Macchi, A. Sironi, L. Garlaschelli. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 39:5(2010), pp. 1188-1190.
Titolo: | Four tetrairidium carbonyl clusters linked by six diphosphino ligands : synthesis and X-ray structure of [{Ir4(CO)9}4(dppmb)6] (dppmb = 1,4-bis(diphenylphosphinomethyl)benzene |
Autori: | PELI, GIULIA (Primo) DAGHETTA, MATTEO ANTONIO AMBROGIO (Secondo) SIRONI, ANGELO AGOSTINO DANIELE (Penultimo) GARLASCHELLI, LUIGI (Ultimo) |
Parole Chiave: | iridium carbonyl cluster ; phosphanes |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica Settore CHIM/03 - Chimica Generale e Inorganica |
Data di pubblicazione: | 2010 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/B918770G |
Appare nelle tipologie: | 01 - Articolo su periodico |