Tetrairidium carbonyl clusters are potentially useful connectors for multidimensional functionalized frameworks with organic bis-phosphines as linkers. The reaction of Ir4(CO)12 and 1,4-bis(diphenylphosphinomethyl)benzene produces an oligomeric cyclic structure, made of 4 connectors and 6 linkers, a possible intermediate in the formation of three dimensional networks.

Four tetrairidium carbonyl clusters linked by six diphosphino ligands : synthesis and X-ray structure of [{Ir4(CO)9}4(dppmb)6] (dppmb = 1,4-bis(diphenylphosphinomethyl)benzene / G. Peli, M.A.A. Daghetta, P. Macchi, A. Sironi, L. Garlaschelli. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 39:5(2010), pp. 1188-1190. [10.1039/B918770G]

Four tetrairidium carbonyl clusters linked by six diphosphino ligands : synthesis and X-ray structure of [{Ir4(CO)9}4(dppmb)6] (dppmb = 1,4-bis(diphenylphosphinomethyl)benzene

G. Peli
Primo
;
M.A.A. Daghetta
Secondo
;
A. Sironi
Penultimo
;
L. Garlaschelli
Ultimo
2010

Abstract

Tetrairidium carbonyl clusters are potentially useful connectors for multidimensional functionalized frameworks with organic bis-phosphines as linkers. The reaction of Ir4(CO)12 and 1,4-bis(diphenylphosphinomethyl)benzene produces an oligomeric cyclic structure, made of 4 connectors and 6 linkers, a possible intermediate in the formation of three dimensional networks.
iridium carbonyl cluster ; phosphanes
Settore CHIM/03 - Chimica Generale e Inorganica
Settore CHIM/03 - Chimica Generale e Inorganica
2010
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/146093
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