Tetrairidium carbonyl clusters are potentially useful connectors for multidimensional functionalized frameworks with organic bis-phosphines as linkers. The reaction of Ir4(CO)12 and 1,4-bis(diphenylphosphinomethyl)benzene produces an oligomeric cyclic structure, made of 4 connectors and 6 linkers, a possible intermediate in the formation of three dimensional networks.
Four tetrairidium carbonyl clusters linked by six diphosphino ligands : synthesis and X-ray structure of [{Ir4(CO)9}4(dppmb)6] (dppmb = 1,4-bis(diphenylphosphinomethyl)benzene / G. Peli, M.A.A. Daghetta, P. Macchi, A. Sironi, L. Garlaschelli. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 39:5(2010), pp. 1188-1190. [10.1039/B918770G]
Four tetrairidium carbonyl clusters linked by six diphosphino ligands : synthesis and X-ray structure of [{Ir4(CO)9}4(dppmb)6] (dppmb = 1,4-bis(diphenylphosphinomethyl)benzene
G. PeliPrimo
;M.A.A. DaghettaSecondo
;A. SironiPenultimo
;L. GarlaschelliUltimo
2010
Abstract
Tetrairidium carbonyl clusters are potentially useful connectors for multidimensional functionalized frameworks with organic bis-phosphines as linkers. The reaction of Ir4(CO)12 and 1,4-bis(diphenylphosphinomethyl)benzene produces an oligomeric cyclic structure, made of 4 connectors and 6 linkers, a possible intermediate in the formation of three dimensional networks.
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