Perfluorocarbon chains, that is, perfluoroethyl, CF3CF2-, perfluoro-n-propyl, CF3CF2CF2-,perfluoro-iso-propyl, (CF3)2CF-, and perfluoropolyether (PFPE) residues, were covalently bonded on the surface of a carbon black using perfluorodiacyl and PFPE peroxides. Thermal decomposition of the fluorinated peroxides allows the covalent linkage of fluorinated radicals to the polycyclic aromatic structure of the carbon black. Contact anglemeasurements in agreement with XPS data revealed a gradual enhancement of the water repellence with increasing fluorine content on the surface.When perfluoroalkyl chains were bonded to the carbon black the morphology and the surface areas of the modified carbonaceous materials were mostly retained as shown by BET and SEM nalyses.
Highly hydrophobic carbon black obtained by covalent linkage of perfluorocarbon and perfluoropolyether chains on the carbon surface / M. Sansotera, C.L.M. Bianchi, G. Lecardi, G. Marchionni, P. Metrangolo, G. Resnati, W. Navarrini. - In: CHEMISTRY OF MATERIALS. - ISSN 0897-4756. - 21:19(2009), pp. 4498-4504.
|Titolo:||Highly hydrophobic carbon black obtained by covalent linkage of perfluorocarbon and perfluoropolyether chains on the carbon surface|
BIANCHI, CLAUDIA LETIZIA MADDALENA (Secondo)
|Settore Scientifico Disciplinare:||Settore CHIM/04 - Chimica Industriale|
Settore CHIM/07 - Fondamenti Chimici delle Tecnologie
|Data di pubblicazione:||2009|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1021/cm901271q|
|Appare nelle tipologie:||01 - Articolo su periodico|