(Figure Presented) Under pressure: characterization of the high-pressure phase of crystalline [Co2(CO)6(PPh3) 2] has provided the first structural evidence for the transformation from a staggered to eclipsed arrangement of the equatorial carbonyl ligands in a dimeric transition-metal complex (see picture). A comparison with the same phenomenon observed at low temperature (though arrested in the very early stages) is presented.
Staggered to eclipsed conformational rearrangement of [Co2(CO)6(PPh3)2] ] in the solid state: An X-ray diffraction study at high pressure and low temperature / N. Casati, P. Macchi, A. Sironi. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 44:47(2005), pp. 7736-7739.
Staggered to eclipsed conformational rearrangement of [Co2(CO)6(PPh3)2] ] in the solid state: An X-ray diffraction study at high pressure and low temperature
N. CasatiPrimo
;P. MacchiSecondo
;A. SironiUltimo
2005
Abstract
(Figure Presented) Under pressure: characterization of the high-pressure phase of crystalline [Co2(CO)6(PPh3) 2] has provided the first structural evidence for the transformation from a staggered to eclipsed arrangement of the equatorial carbonyl ligands in a dimeric transition-metal complex (see picture). A comparison with the same phenomenon observed at low temperature (though arrested in the very early stages) is presented.
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