Strong light-matter coupling gives rise to polaritons – hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article reviews the main architectures supporting polariton formation, including photonic microcavities, plasmonic nanostructures, open cavities and metasurfaces, and outlines how inorganic semiconductors, organic aggregates and hybrid systems access strong and ultrastrong coupling. Key phenomena such as coherent dynamics, vibronic interactions, dark‑state reservoirs and polariton‑mediated energy and electron transport are discussed, together with the experimental and theoretical tools used to study them. We highlight examples where strong coupling modifies charge transport, energy flow and chemical reactivity, and we summarize emerging regimes, including intermediate and dark‑strong coupling, that broaden the landscape of hybrid light-matter physics.
Strong light-matter interactions in hybrid polaritonic systems / B. Johns, A.S.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - (2026), pp. 1-27. [Epub ahead of print] [10.1039/d6cc02672a]
Strong light-matter interactions in hybrid polaritonic systems
M. Vanzan;F. Baletto;
2026
Abstract
Strong light-matter coupling gives rise to polaritons – hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article reviews the main architectures supporting polariton formation, including photonic microcavities, plasmonic nanostructures, open cavities and metasurfaces, and outlines how inorganic semiconductors, organic aggregates and hybrid systems access strong and ultrastrong coupling. Key phenomena such as coherent dynamics, vibronic interactions, dark‑state reservoirs and polariton‑mediated energy and electron transport are discussed, together with the experimental and theoretical tools used to study them. We highlight examples where strong coupling modifies charge transport, energy flow and chemical reactivity, and we summarize emerging regimes, including intermediate and dark‑strong coupling, that broaden the landscape of hybrid light-matter physics.| File | Dimensione | Formato | |
|---|---|---|---|
|
d6cc02672a.pdf
accesso aperto
Tipologia:
Post-print, accepted manuscript ecc. (versione accettata dall'editore)
Licenza:
Creative commons
Dimensione
2.53 MB
Formato
Adobe PDF
|
2.53 MB | Adobe PDF | Visualizza/Apri |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.




