Attempts to synthesize a phenanthroline palladium(0) complex with an η2-coordinated nitrosoarene starting from a palladium(ii) precursor and the corresponding aryl hydroxylamine afforded instead apparent palladium(i) metallacyclic complexes that, on a closer inspection, were proven to be Pd(ii) complexes with a new kind of radical-anionic nitrosoarene ligand.
A non-innocent radical-anionic nitrosoarene ligand regularizes a formal palladium(i) complex to palladium(ii) / D.R. Ramadan, M.A.F.A.. - In: DALTON TRANSACTIONS. - ISSN 1477-9234. - 55:25(2026), pp. 9597-9604 (S1 - S23). [10.1039/D6DT01038E]
A non-innocent radical-anionic nitrosoarene ligand regularizes a formal palladium(i) complex to palladium(ii)
D.R. RamadanPrimo
;M.A.F. AbdellatifSecondo
;F. Ferretti;P. Macchi;F. Ragaini
Ultimo
2026
Abstract
Attempts to synthesize a phenanthroline palladium(0) complex with an η2-coordinated nitrosoarene starting from a palladium(ii) precursor and the corresponding aryl hydroxylamine afforded instead apparent palladium(i) metallacyclic complexes that, on a closer inspection, were proven to be Pd(ii) complexes with a new kind of radical-anionic nitrosoarene ligand.
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